A Short Review of Some Examples of the Binding of Fullerenes C60 to Transition Metal Complexes
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Abstract
Fullerenes C60 are molecules composed of carbon atoms arranged in a hollow spherical structure. They have been found to bind to transition metal complexes, which are molecules composed of a metal atom and one or more other atoms. This binding has been found to be very strong, with the fullerene molecules forming a protective shell around the transition metal complex. This has potential applications in a range of fields, such as biochemistry and nanotechnology. This review provides a description of some of the examples of such binding, including the different types of transition metals involved, the binding energies associated and the different structures observed.
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The discovery of Fullerenes earned its authors, H. Kroto, R. Curl and R. Smalley, the award of the Nobel Prize in Chemistry in 1996.
H. W. Kroto, J. R. Heath, S. C. O'Brien, R. F. Curl, R. E. Smalley, Nature
, 318,162. [CrossRef]
W. Krätschmer, L. D. Lamb, K. Fostiropoulos, D. R. Huffman, Nature1990, 347, 354. [CrossRef]
This extract contains mainly C 60 (about 60%) and C 70 (about 20%); the other fullerenes (C 76, C 78, C 82, C 84, C 90, C 94 and C 96) are much less abundant.
P. W. Fowler, Chem. Phys. Lett. 1986, 131, 444; P. W. Fowler and C. M. Quinn, Theor. Chim. Acta 1986, 70, 333. [CrossRef]
L. W. Tutt, A. Kost, Nature 1992, 356, 225. [CrossRef]
F. Negri, G. Orlandi, F. Zerbetto. J. Am. Chem. Soc. 1992, 114, 8. [CrossRef]
Q. Xie, E. Perez-Cordero, L. Echegoyen, J. Am. Chem. Soc. 1992, 114, 3978. [CrossRef]
A. Hirsch, The Chemistry of the Fullerenes, Thieme, Stuttgart, 1994. [CrossRef]
Fullerenes: from Synthesis to Optoelectronic Properties ( Eds. D. M. Guldi and N. Martin), Kluwer Academic Publisher, Dordrecht (The Netherlands), 2002.
P. W. Stephens, D. Cox, J. W. Lauher, L. Mihaly, J. B. Wiley, P.-M. German, A. Hirsch, K. Holczer, Q. Li, J. D. Thompson, F. Wudl, Nature 1992, 355, 331; G. Sparn, J. D; Thompson, P.-M. German, Q. Li, F. Wudl, K. Holczer, P. W. Stephens, Solid State Commun. 1992, 82, 779; C. Bossard, S. Rigaut, D. Astruc, M.-H. Delville, G. Felix, A. Fevrier-Bouvier, J. Amiall, S. Flandrois, P. Delhaes, J. Chem. Soc. , Chem. Comm. 1993, 333. [CrossRef]
D. M. Guldi, G. Torres-Garcia, J. Mattay, J. Phys. Chem. A 1998, 102, 9679; N. Armaroli, F. Barigelletti, P. Ceroni, J.-F. Eckert, J.-F. Nicoud, J.-F. Nierengarten, Chem. Common. 2000, 599; J.-F. Eckert, J.-F. Nicoud, J.-F. Nierengarten, S.-G. Liu, L. Echegoyen, F. Barigelletti, N. Armaroli, L. Ouali, G. Hadziioannou, J. Am. Chem. Soc. 2000, 122, 7467. [CrossRef]
R. M. Williams, J. M. Zwier, J. W. Verhoeven, J. Am. Chem. Soc. 1995, 117, 4093; Y.- P. Sun, B. Ma, G. E. Lawson, Chem. Phys. Lett. 1995, 233, 57; H. Imahori, Y. Sakata, Adv. Suppress. 1997, 9, 537; D. M. Guldi, M. Maggini, G. Scorrano, M. Prato, J. Am. Chem. Soc. 1997, 119, 974; M. Maggini, D. M. Guldi, S. Mondini, G. Scorrano, F. Paolucci, P. Ceroni, S. Roffia, Chem. Eur. J. 1998, 4, 1992; K. George Thomas, V. Biju, M. V. George, D. M. Guldi, P. V. Kamat, J. Phys. Chem. B 1999, 103, 8864; M. D. Meijer, G. P. M. van Klink, G. van Koten, Coord. Chem. Rev. 2002, 230 , 141. [CrossRef]
Machkour A, Thallaj NK, Benhamou L, Lachkar M, Mandon D.Chemistry. 2006 Aug 25;12(25):6660-8.P 6660-6661-6662-6663. [CrossRef]
Thallaj, N., Machkour, A., Mandon, D., Welter, R., New. J. Chem., 2005, 29, 1555 – 1558. [CrossRef]
Thallaj, N. K. Damascus University Journal for Basic Sciences. 34 (1) 2018.
Thallaj. N. K. Journal of AlBaath University (39) 2017.
Thallaj. N. K. Tishreen University Journal for Research and Scientific Studies 38 (6) 2016.
Thallaj NK, Rotthaus O, Benhamou L, Humbert N, Elhabiri M, Lachkar M, Welter R, Albrecht-Gary AM, Mandon D. Chemistry. 2008;14(22):6742-53.P6745-6746-6747.. [CrossRef]
Wane A, Thallaj NK, Mandon D. Chemistry. 2009 Oct 12;15(40):10593-602. P10594-10595-10595. [CrossRef]
Thallaj NK, Orain PY, Thibon A, Sandroni M, Welter R, Mandon D. Inorg Chem. 2014 Aug 4;53(15):7824-36. P7826-7827-7828. [CrossRef]
N. K. Thallaj, J. Przybilla, R. Welter and D. Mandon, J. Am. Chem. Soc. 2008, 130, 2414-2415. [CrossRef]
N. K. Thallaj, D. Mandon and K. A. White, Eur. J. of Inorg. Chem., 2007, 44–47. [CrossRef]
N. K. Thallaj, A. Machkour, D. Mandon and R. Welter, New J. Chem., 2005, 29, 1555–1558. [CrossRef]
Thallaj, N.; International journal of applied chemistry and biological sciences 2021, 2 (4), 65-77.
Thallaj, N.; Indian Journal of Advanced Chemistry (IJAC)2021, 1 (2), . [CrossRef]
Thallaj, N.; International Journal of Research Publication and Reviews (IJRPR)2021, 2, 10, 951-959
L. Labban, N. Thallaj, Z. Malek; International Journal of Medical Studies, 2020, 5, No 12, 23-36. [CrossRef]
L. Labban, M. Kudsi, Z. Malek, N. Thallaj; Advances in Medical, Dental and Health Sciences, 2020,3, 3,45-48. [CrossRef]
L. Labban, N. Thallaj, M. Al Masri; Journal of Advanced Research in Food Science and Nutrition, 2020,3,1,34-41. [CrossRef]
Thallaj, N; agha, M. I ,H;, nattouf; A.H; katib, CH; karaali, A; Moustapha, A; Labban L;open access library journal, 2020,7,5,1-21. [CrossRef]
L. labban; N. thallaj; A. labban; archives of medicine, 2020, 12, 2:8, 1-5. [CrossRef]
L. labban; N. thallaj; international journal of herbal medicine,2020, 8, 2, 33-37.
L. Labban, N. Thallaj, Z. Malek; Journal of Medical Research and Health Sciences, 2019, 2, 11, 784-787.
L. labban N. Thallaj; acta scientific nutritional health, 2019, 3,10, 7-12. [CrossRef]
Malek, Z.S.; Sage D.; Pevet, P.; Raison, S.; Endocrinology 2007, 148 (11), 5165-5173. [CrossRef]
Malek, Z.S.; Dardente, H.; Pevet, P.; Raison, S.; European Journal of Neuroscience 2005, 22 (4), 895-901. [CrossRef]
Malek, Z.S.; Pevet, P.; Raison, S.; Neuroscience 2004, 125 (3), 749-758. [CrossRef]
Malek, Z.S.; Labban, L.; The International Journal of Neuroscience, 2020, 1-7.
Malek, Z.S.; Labban, L.; European Journal of Pharmaceutical and Medical Research 2019, 6 (11), 527-532.
Malek, Z.S.; Journal of AlBaath University 2018, 40 (4), 39-62.
Malek, Z.S.; Tishreen University Journal for Research and Scientific Studies, 2018, 40.
ZS Malek, LM Labban; International Journal of Neuroscience, 2021,131 (12), 1155-1161. [CrossRef]
ZS Malek, LM Labban; Journal of current research in physiology and pharmacology, 2020, 4, (1),1-5.
L.M. Labban, M. M. Alshishkli, A. Alkhalaf, Z. Malek; J. Adv. Res. Dent. Oral Health, 2017, 2(3&4), 1-4.
L Labban, ZS Malek, Open Access Library Journal, 2018, 5 (07), 1-11. [CrossRef]
L Labban, ZS Malek, Ann Food Nutr Res J, 2019,1 ,1
Labban, L. and N. Thallaj, 2019. Acta Scient. Nutr. Health, 3: 7-12. [CrossRef]
Y. alhomush, Z. malek, A. Abboud, N.Thallaj, Research Journal of Pharmacy and Technology, 2022, 15, 10.
N.Thallaj, Tishreen university journal,2022,44, 1, 59-77.
N.Thallaj, Tishreen university journal,2022,44,2, 87-105.
Z. Malek, H. Dardente, S. Raison, P. Pevet, Mesocricetus auratus neuronal tryptophan hydroxylase mRNA, partial cds, 2003, GenBank, AY345967.1.
N.Thallaj. Indian journal of advanced chemistry, 1, 3, 2022. 10-14. [CrossRef]
A. Abbood, N Thallaj, (2023). 7,(1), Arab Journal of Pharmaceutical Sciences.
N Thallaj, (2023). 44,(6),21-29. Tishreen University Journal-Medical Sciences Series.
A.Abbood, Z.Malek, N.Thallaj. 2022 15, 11, 4935-4939. Research Journal of Pharmacy and Technology. [CrossRef]
A.Abbood, Z.Malek, Y.Al-Homsh, N.Thallaj. 2022 15, 10, 4727-4732. Research Journal of Pharmacy and Technology. [CrossRef]
N Thallaj, (2023). 45,(1). Tishreen University Journal-Medical Sciences Series.
A.Abbood, N Thallaj, (2023). 45,(2). Tishreen University Journal-Medical Sciences Series.
L. Alallan, Z.malek, (2023). 45,(1). Tishreen University Journal-Medical Sciences Series.